By Carsten Bolm, F. Ekkehardt Hahn
Using secondary interactions for the activation of non-reactive substrates constitutes a brand new and smooth technique in catalysis.
this primary entire remedy of this significant examine box covers the total box and divulges the hyperlinks among a number of the chemical disciplines. It hence adopts an interdisciplinary process, making it of curiosity to the total chemical community.
A needs to for natural, inorganic, catalytic and complicated chemists, in addition to these operating with/on organometallics.Content:
Chapter 1 Chemistry of Metalated box Molecules (pages 1–15): Berthold Kersting
Chapter 2 The Chemistry of Superbasic Guanidines (pages 17–37): Jorg Sundermeyer, Volker Raab, Ekatarina Gaoutchenova, Udo Garrelts, Nuri Abacilar and Klaus Harms
Chapter three Iron Complexes and Dioxygen Activation (pages 39–51): Thomas Nebe, Jing?Yuan Xu and Siegfried Schindler
Chapter four Tuning of buildings and houses of Bispidine Complexes (pages 53–63): Peter Comba and Marion Kerscher
Chapter five Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for purposes in Homogeneous Catalysis (pages 65–88): Anna?Katharina Pleier, Yu sunlight, Anett Schubert, Dirk Zabel, Claudia may possibly, Andreas Reis, Gotthelf Wolmershauser and Werner R. Thiel
Chapter 6 Square?Pyramidal Coordinated Phosphine Iron Fragments: A story of the unforeseen (pages 89–102): Andreas Grohmann and Stephan Kohl
Chapter 7 Regioselective Catalytic job of Complexes with NH, NR?Substituted Heterocyclic Carbene Ligands (pages 103–122): Siegfried R. Waldvogel, Anke Spurg and Prof. Dr. F. Ekkehardt Hahn
Chapter eight Functionalized Cycloheptatrienyl?Cyclopentadienyl Sandwich Complexes as development Blocks in Metallo?Supramolecular Chemistry (pages 123–146): Matthias Tamm
Chapter nine Monosaccharide Ligands in Organotitanium and Organozirconium Chemistry (pages 147–164): Peter Kitaev, Daniela Zeysing and Jurgen Heck
Chapter 10 Reactions of C?F Bonds with Titanocene and Zirconocene: From Secondary interplay through Bond Cleavage to Catalysis (pages 165–182): Uwe Rosenthal, Vladimir V. Burlakov, Perdita Arndt, Anke Spannenberg, Ulrike Jager?Fiedler, Marcus Klahn and Marko Hapke
Chapter eleven Bisazines within the Coordination Sphere of Early Transition Metals (pages 183–207): Ruediger Beckhaus
Chapter 12 Bifunctional Molecular structures with Pendant Bis(pentafluorophenyl)boryl teams: From Intramolecular CH?Activation to Heterolytic Dihydrogen Splitting (pages 209–230): Michael Hill, Christoph Herrmann, Patrick Spies, Gerald Kehr, Klaus Bergander, Roland Frohlich and Gerhard Erker
Chapter thirteen Ruthenium?Containing Polyoxotungstates: constitution and Redox job (pages 231–243): Ulrich Kortz
Chapter 14 From NO to Peroxide Activation via version Iron(III) Complexes (pages 245–272): Alicja Franke, Natalya Hessenauer?Ilicheva, Joo?Eun Jee and Rudi van Eldik
Chapter 15 artificial Nitrogen Fixation with Molybdenum and Tungsten Phosphine Complexes: New advancements (pages 273–296): Gerald Stephan and Felix Tuczek
Chapter sixteen Directed C?H Functionalizations (pages 297–312): Prof. Dr. Carsten Bolm
Chapter 17 improvement of Novel Ruthenium and Iron Catalysts for Epoxidation with Hydrogen Peroxide (pages 313–337): guy relations Tse, Bianca Bitterlich and Matthias Beller
Chapter 18 Pentacoordinating Bis(oxazoline) Ligands with Secondary Binding websites (pages 339–348): Caroline A. Schall, Michael Seitz, Anja Kaiser and Oliver Reiser
Chapter 19 Flavin Photocatalysts with Substrate Binding websites (pages 349–358): Harald Schmaderer, Jiri Svoboda and Burkhard Konig
Chapter 20 New Catalytic Cu?, Pd? and Stoichiometric Mg?, Zn?Mediated Bond Activations (pages 359–377): Tobias Thaler, Hongjun Ren, Nina Gommermann, Giuliano C. Clososki, Christoph J. Rohbogner, Stefan H. Wunderlich and Paul Knochel
Chapter 21 From Cobalt(II)?Activated Molecular Oxygen to Hydroxymethyl?Substituted Tetrahydrofurans (pages 379–396): Barbara Menendez Perez, Dominik Schuch and Jens Hartung
Chapter 22 Regiodivergent Epoxide commencing (pages 397–409): Andreas Gansauer, Florian Keller, Chun?An Fan and Peter Karbaum
Chapter 23 Supramolecular packing containers: Host?Guest Chemistry and Reactivity (pages 411–425): Markus Albrecht
Chapter 24 Self?Assembly of Dinuclear Helical Metallosupramolecular Coordination Compounds (pages 427–446): Ulf Kiehne, Jens Bunzen and Arne Lutzen
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Additional info for Activating Unreactive Substrates: The Role of Secondary Interactions
2001) Angewandte Chemie – International Edition, 40, 3988–3990. M. G. (1986) Inorganic Chemistry, 25, 552–558. , K€ass, S. and Kersting, B. (2006) Dalton Transactions, 3812–3821. , Klod, S. and Kleinpeter, E. (2004) European Journal of Inorganic Chemistry, 4402–4411. N. and Diederich, F. (1990) Pure and Applied Chemistry, 62, 2227–2236. 59 Hausmann, J. (2001) Diplomarbeit, Universit€at Freiburg. G. and Welter, R. (2002) Angewandte Chemie – International Edition, 41, 2593–2596. J. (2004) Chemistry - A European Journal, 10, 1716–1728.
The frozen green solution of our superoxo complex turned out to be epr silent in the X-band. Furthermore, we were not able to transfer the green crystals into a SQUID capillary at temperatures below À40 C. However, we were able to employ the Evans method for the measurement of the magnetic susceptibility in acetone at 190 K [30, 31]. 83 mB of a ground-state triplet species. This explains the nmr results, with large paramagnetic shifts, that were obtained. The message is that the spins in this end-on superoxo complex are ferromagnetically coupled, whereas they are antiferromagnetically coupled in all side-on superoxo complexes known so far.
This might proceed either via an inner-sphere mechanism and a Cu(I) precoordinated oxidant or via an outer-sphere mechanism. The result of a single-electron transfer would be the formation of oxidant radical anions coordinated to Cu(II) and elimination of stable leaving groups N2 or PhI. 9 Formation and degradation pathways of a proposed mononuclear oxo species [(DMEG3tren)Cu(NTs)]þ . Molecular structure of [(DMEG3trenNTs)Cu]ClO4. electronic Cu structures are plausible for the activated oxidant complex, a radical anion coordinated at Cu(II) (form A) or a fully reduced closed-shell anion [O]2À or [NTs]2À coordinated at a diamagnetic Cu(III) site (form B).
Activating Unreactive Substrates: The Role of Secondary Interactions by Carsten Bolm, F. Ekkehardt Hahn